科學(xué)研究

化工學(xué)院黃文歡團(tuán)隊(duì)近期在《Angew Chem.》《Adv. Sci.》等雜志上發(fā)表一系列研究成果

2023-07-13 08:57 文、圖/化工學(xué)院 點(diǎn)擊:[]

近期,我?;瘜W(xué)與化工學(xué)院黃文歡團(tuán)隊(duì)圍繞雜化多孔微納結(jié)構(gòu)的精確構(gòu)造及能量轉(zhuǎn)換存貯性能的調(diào)控方面取得了多項(xiàng)重要進(jìn)展,連續(xù)在國(guó)際頂級(jí)期刊Angew Chem.Int. Ed.、Advanced Science、Carbon Energy等期刊上發(fā)表一系列研究論文。

【成果1】高密度原子CoFe摻雜多級(jí)孔吸波材料的設(shè)計(jì)及納米渦旋偶極及磁疇的精確構(gòu)造

黃文歡課題組與復(fù)旦大學(xué)車仁超教授合作設(shè)計(jì)低CoFe含量的含能MOF(金屬三氮唑)前驅(qū)體,通過三氮唑400度左右的“爆炸”反應(yīng)可以成功合成具有超低金屬負(fù)載、超低密度的具有多級(jí)孔結(jié)構(gòu)的CoFe摻雜三維碳海綿材料。實(shí)現(xiàn)對(duì)金屬原子級(jí)分散、材料介電性能、耦合性能、阻抗匹配等的可控調(diào)控。

文章捕獲了材料在不同溫度下(400、600、800、1000oC)的產(chǎn)物,通過同步輻射、洛倫茲電鏡,結(jié)合理論計(jì)算,揭示了材料隨著溫度的升高其多孔碳基底孔結(jié)構(gòu)從大孔、介孔到微孔、納米孔的演變,以及在基底上金屬?gòu)膱F(tuán)簇狀態(tài)向單原子狀態(tài)的演變、原子之間的相互作用,這些微觀的原子及孔結(jié)構(gòu)誘導(dǎo)了體系內(nèi)納米渦旋極化及渦旋磁疇的產(chǎn)生。最終實(shí)現(xiàn)了該材料體系的吸收強(qiáng)度、X/Ku波段的全吸收的雙重性能調(diào)控。該成果發(fā)表于《Adv. Sci.》期刊上。

【成果23D MOF基膜原位生成富含LiF的Janus異質(zhì)結(jié)構(gòu)SEI穩(wěn)定固態(tài)Li金屬電池

黃文歡課題組與蘇慶梅教授、揚(yáng)州大學(xué)龐歡教授合作構(gòu)建了離子液體限域MOF(金屬咪唑)/聚合物三維多孔Janus膜,并在充放電循環(huán)過程中原位形成了富含LiF/Li3N的固態(tài)電解質(zhì)界面(SEI)膜。此三維Janus膜具有快速的鋰離子傳輸通道、優(yōu)異的室溫離子電導(dǎo)率(8.17×10-4S cm-1)和高的鋰離子遷移數(shù)(0.82)。該復(fù)合電解質(zhì)隔膜具有高熱穩(wěn)定性和機(jī)械強(qiáng)度的膜用于固態(tài)Li∥LiFePO4和Li∥NCM-811電池,甚至在軟包電池中均顯示出優(yōu)異的倍率性能和超長(zhǎng)的壽命。

文章詳細(xì)的通過冷凍透射電鏡對(duì)SEI中原位形成的LiF和Li3N納米晶體以及鋰枝晶的沉積進(jìn)行了可視化監(jiān)測(cè),并對(duì)電池充放電過程中結(jié)構(gòu)演變進(jìn)行了理論模擬和動(dòng)力學(xué)分析,揭示了電池充放電過程中的界面行為及機(jī)理。此工作為新型MOF基固態(tài)電解質(zhì)的構(gòu)建提供了一種新的思路和方法。該成果發(fā)表于《AngewChem. Int. Ed.》期刊上。

【成果3】單原子高價(jià)態(tài)Mo“陷阱”捕獲電子誘導(dǎo)電荷聚集促進(jìn)光催化產(chǎn)氫

黃文歡課題組與阿卜杜拉國(guó)王科技大學(xué)張華彬、Magnus Rueping教授合作,將高氧化態(tài)的Mo原子作為電子陷阱,以單原子形式植入Cd0.5Zn0.5S晶格中,降低了CZS的帶隙并可以成功捕獲光生電子,增強(qiáng)自由基數(shù)量。3.11 wt% Mo負(fù)載的CZS@Mo表現(xiàn)出了良好的光催化析氫性能(λ>420 nm)及穩(wěn)定性。

文章詳細(xì)通過瞬態(tài)吸收光譜監(jiān)測(cè)了CZS和CZS @Mo的光生電子動(dòng)力學(xué)行為,證實(shí)了Mo電子“陷阱”對(duì)電子-空穴復(fù)合的抑制作用。此外,DFT理論計(jì)算表明Mo原子周圍的高電子密度,反應(yīng)歷程的吸附自由能解釋了Mo位點(diǎn)的良好催化動(dòng)力學(xué),證實(shí)了Mo原子的電子捕獲效應(yīng)及其在光催化析氫中的反應(yīng)機(jī)理。本文的研究結(jié)果為可控設(shè)計(jì)和制備具有良好應(yīng)用前景的單原子光催化制氫催化劑提供了重要的理論依據(jù)。該成果發(fā)表于《AngewChem. Int. Ed.》期刊上。

【成果4】綜述論文:面向碳中和構(gòu)筑非均相催化劑催化轉(zhuǎn)化二氧化碳為羧酸的研究進(jìn)展

陜西科技大學(xué)黃文歡教授、阿卜杜拉國(guó)王科技大學(xué)張華彬教授,中國(guó)石油大學(xué)智林杰教授,愛爾蘭三一學(xué)院Max García-Melchor教授,北京化工大學(xué)于樂教授,清華大學(xué)王定勝教授共同總結(jié)了非均相催化劑用于CO2制備羧酸化合物的構(gòu)筑策略,為活化,轉(zhuǎn)化二氧化碳為羧酸等高附加值產(chǎn)物提供了明確的指導(dǎo)和重要參考。本文首先分別從光,電,熱三個(gè)方面闡述了相應(yīng)領(lǐng)域催化的機(jī)理過程,羧酸產(chǎn)物的類型和商業(yè)價(jià)值,以及目前取得的研究進(jìn)展。其次從復(fù)合催化劑,雜原子參雜,形貌調(diào)控、表面功能化四個(gè)方面系統(tǒng)總結(jié)分析了非均相催化劑的合成,調(diào)控策略,強(qiáng)調(diào)了催化位點(diǎn)中配位環(huán)境,電子效應(yīng),空間效應(yīng)等對(duì)其活性的影響,以及催化劑結(jié)構(gòu)與活性的內(nèi)在構(gòu)效關(guān)系。最后,展望了CO2制備羧酸化合物面臨的挑戰(zhàn)以及未來的研究方向,為推動(dòng)CO2的利用和羧酸化學(xué)品的可控制備提供了重要的啟示。該成果發(fā)表于《CarbonEnergy》期刊上。

【成果5】燃燒法誘導(dǎo)含能MOF向金屬氧化物多級(jí)孔碳材料的結(jié)構(gòu)及吸波性能調(diào)控

黃文歡課題組與南京理工大學(xué)吳凡教授合作,以含能金屬有機(jī)骨架為材料,通過燃燒的原位轉(zhuǎn)化工藝,成功制備了具有超高多孔微納結(jié)構(gòu)和均勻分散的CoFe單元的三維磁性分子海綿(表示為CoFe@PCS)。其獨(dú)特的框架結(jié)構(gòu)和集成的磁介電元件使其具有高效的微波吸收。在厚度為2.57 mm處,CoFe@PCS的最小反射損耗為?70.10 dB,有效吸收帶寬為8.64 GHz。更重要的是,深入剖析了磁性海綿內(nèi)部的損耗機(jī)制和能量耗散,揭示了弛豫主導(dǎo)的介質(zhì)損耗和介電-磁協(xié)同作用。這項(xiàng)工作為高性能吸收體的目標(biāo)設(shè)計(jì)和制造提供了一種巧妙的方法。該成果發(fā)表于《Advanced Composites and Hybrid Materials》期刊上。

【成果6】主客體框架原位水熱合成超高性能POMOF@CoNi-水滑石超級(jí)電容器電極材料

張亞男、黃文歡教授,通過主客體效應(yīng)水熱合成雜多酸摻雜的-銅基金屬有機(jī)骨架,通過水熱刻蝕的方法構(gòu)造了POMOF@CoNi-LDH納米片結(jié)構(gòu)。材料類因其超高的比表面積、豐富的電化學(xué)活性位點(diǎn)和,作為超級(jí)電容器電極材料,在1A·g-1時(shí)表現(xiàn)出了333.61 mAh·g-1的高比容量。在混合超級(jí)電容器中POMOF@CoNi-LDH/活性炭(AC),能量密度高達(dá)80.8 Wh·kg-1、功率密度750.7 W·kg-1。更重要的是,,在10A·g-1條件下充放電5000次后,材料表現(xiàn)出優(yōu)異的電容保持(79%),本文提供了一個(gè)高性能儲(chǔ)能電極材料的合成方法及策略。該成果以O(shè)utsideFrontCover發(fā)表于《Chin. J. Chem.》期刊上。

【成果7】CoNi摻雜中空碳化鉬球的可控合成及電磁波吸收性能的調(diào)控

黃文歡教授團(tuán)隊(duì),通過設(shè)計(jì)雙金屬CoNi摻雜的晶態(tài)雜化金屬咪唑框架,利用化學(xué)刻蝕及熱處理的方法原位構(gòu)造了超薄的中空CoNi摻雜的碳化鉬球,成功的調(diào)控了材料的介電損耗、磁耦合和阻抗匹配性能。材料在負(fù)載量為15wt %時(shí),表現(xiàn)出了最優(yōu)的電磁波吸收性能RLmin=-60.05 dB。該成果受邀發(fā)表于《Chin. J. Chem.》期刊上。

【作者簡(jiǎn)介】

黃文歡,陜西省“科學(xué)家+工程師”創(chuàng)新團(tuán)隊(duì)首席科學(xué)家、陜西省科技新星,近年來主持國(guó)家項(xiàng)目2項(xiàng)、省部級(jí)各類科研項(xiàng)目7項(xiàng)、教學(xué)項(xiàng)目2項(xiàng),獲得陜西省高??茖W(xué)技術(shù)獎(jiǎng)一等獎(jiǎng)1項(xiàng),陜西省人才計(jì)劃項(xiàng)目2項(xiàng)。在Angew Chem. Int. Ed.、Nano-Micro Letters、Carbon Energy、Matter、Journal of Materials Chemistry A、Energy & Environmental Materials、Chemical Engineering Journal、Materials Chemistry Frontiers、Chemical Communications、Carbon、Journal of Power Sources、Nanoscale、Chemistry-A European Journal、Inorganic Chemistry等國(guó)際期刊上發(fā)表SCI論文50余篇,其中受邀撰寫綜述6篇,高被引論文7篇,熱點(diǎn)論文2篇,授權(quán)國(guó)家發(fā)明專利4項(xiàng)。曾受邀請(qǐng)?jiān)趪?guó)內(nèi)外學(xué)術(shù)會(huì)議上作報(bào)告10余次,媒體轉(zhuǎn)載相關(guān)研究成果20余次。組織學(xué)生參加“挑戰(zhàn)杯”課外學(xué)術(shù)科技競(jìng)賽獲得省級(jí)二等獎(jiǎng)2項(xiàng)、三等獎(jiǎng)1項(xiàng),獲得陜西省第六屆研究生創(chuàng)新成果展省級(jí)一等獎(jiǎng)1項(xiàng),省級(jí)創(chuàng)新基金1項(xiàng);培養(yǎng)研究生獲得“優(yōu)秀畢業(yè)生”、“優(yōu)秀碩士畢業(yè)論文”、“國(guó)家獎(jiǎng)學(xué)金”、“研究生高水平科研成果獎(jiǎng)勵(lì)”等。

教師網(wǎng)頁(yè):https://hg.sust.edu.cn/info/1237/5653.htm

【團(tuán)隊(duì)近年來發(fā)表文章】

  1. 2023年

  2. W. Huang,*X. Zhang, J. Chen, Q. Qiu, Y. Kang, K. Pei, S. Zuo, and R. Che*, High-density Nanopore Confined Vortical Dipoles and Magnetic Domains on Hierarchical Macro/Meso/Micro/Nano Porous Ultra-Light Graphited Carbon for Adsorbing Electromagnetic Wave,Advanced Science, 10.1002/advs.202303217.(2022影響因子:15.1)

  3. X. Zhang, Q. Su*, G. Du, B. Xu, S. Wang, Z. Chen, L. Wang,W. Huang*, H. Pang*, Stabilizing Solid-state Lithium Metal Batteries through In Situ Generated Janus-heterarchical LiF-rich SEI in Ionic Liquid Confined 3D MOF/Polymer Membranes,Angew Chem. Int. Ed.,2023, e202304947.(2022影響因子:16.6)

  4. W. Huang, C. Su, C. Zhu, T. Bo, S. Zuo, W. Zhou, Y. Ren, Y. Zhang, J. Zhang, M. Rueping*, H. Zhang*,Isolated Electron Trap-Induced Charge Accumulation for Efficient Photocatalytic Hydrogen Production,Angew Chem., Int. Ed.,2023, e202304634.(VIP paper)(2022影響因子:16.6)

  5. X. Zhang,W. Huang*,L. Yu, M. García-Melchor, D. Wang, L. Zhi* and H. Zhang* Enabling Heterogeneous Catalysis to Achieve Carbon Neutrality: Directional Catalytic Conversion of CO2into Carboxylic Acids,Carbon Energy,2023,e362.(2022影響因子:20.5)

  6. M. Sun, W. Cao, P. Zhu, Z. Xiong, C. Chen, J. Shu*,W. Huang*, Fan Wu*, Thermally tailoring magnetic molecular sponges through self-propagating combustion to tune magnetic-dielectric synergy towards high-efficiency microwave absorption and Attenuation,Advanced Composites and Hybrid Materials,2023, 6: 54.(2022影響因子:20.1)

  7. H. Ruan, L. Zhang*, S. Li, K. Wang,W. Huang,S. Guo*, Carbon Polyhedra Encapsulated Si Derived from Co-Mo Bimetal MOFs as Anode Materials for Lithium-Ion Batteries,Journal of Materials Science & Technology,2023, 159: 91–98.(2022影響因子:10.9)

  8. Y. Li, X. Jin*, Y. Ma, L. Ma, J Liu, P. Zhu, Z. Deng, H. Zhou, W Chen,W. Huang*,Functional decoration on a regenerable bifunctional porous covalent organic framework probe for the rapid detection and adsorption of copper ions,Rare Metals,In press.(2022影響因子:8.8)

  9. Y. Zhang, J. Chen, F. Razq, C. Su, X. Hou,W. Huang*,and H. Zhang*, Polyoxometalate-incorporated host-guest framework derived layered double hydroxide composites for high-performance hybrid supercapacitor,Chinese Journal of Chemistry,2023,41, 75-82.(雜志封面Outside Front Cover)(2022影響因子:5.4)

  10. X. Yang, W. Gao, J. Chen, X. Lu, D. Yang, Y. Kang, Q. Liu, Y. Qing, andW. Huang*, Co-Ni Electromagnetic Coupling in Hollow Mo2C/NC Sphere for Enhancing Electromagnetic Wave Absorbing Performance,Chinese Journal of Chemistry,2023, 41, 64-74.(邀稿,2022影響因子:5.4)

  11. J. Gu, Q. An, J. Chen, Y. He,W. Huang*, Preparation and Responsive Performance study of AuNPs/RGO-MoO2/GCE Composite Modified Electrodes based on its High Sensitivity to Acetaminophen and Dopamine,Inorganic Chemistry Communications,2023, 147, 110282.(2022影響因子:3.8)

  12. Y.Kang, X. Sun, Y. Wang, Y. Zhang, W. Huang*,Design and Synthesis of Copper-Based Simulated Enzyme Induced by Nitrogen Oxidation Ligand and Study of Its Activity.Chinese Journal of Structural Chemistry,2023, 42, 100046.(邀稿,2022影響因子:2.2)

  13. 2022年

  14. W. Huang*, Q. Qiu, X. Yang, S. Zuo, J. Bai, H. Zhang*, K. Pei and R. Che*, Ultrahigh Density of Atomic CoFe-Electron Synergy in Noncontinuous Carbon Matrix for Highly Efficient Magnetic Wave Adsorption.Nano-Micro Letters,2022, 14(1): 96.(2022影響因子:26.6)

  15. C. Feng, Y. Ren, F. Razq,W. Huang*, H. Zhang*, An innovative and ingenious strategy to construct single-atom catalyst for photocatalytic methane conversion,Matter,2022,5, 3086–3111.(2022影響因子:18.9)

  16. W. Huang, T. Bo, S. Zuo, Y. Wang, J. Chen, S. Ould‐Chikh, Y. Li, W. Zhou*, J. Zhang, H. Zhang*, Surface decorated Ni sites for superior photocatalytic hydrogen production,Susmat,2022, 1-10.(邀稿,2022影響因子:28.4)

  17. W. Huang*, W. Gao, S. Zuo, L. Zhang, K. Pei, P. Liu and R. Che*, and H. Zhang*, Hollow MoC/NC Sphere for Electromagnetic Wave Attenuation: Direct Observation of Interfacial Polarization on Nanoscale Hetero-interfaces.Journal of Materials Chemistry A,2022, 10: 1290-1298.(雜志封面Outside Front Cover)(高被引論文)(2022影響因子:11.9)

  18. P. Li, Z. He, X. Li,W. Huang*, and X. Lu*, Fullerene-Intercalated Graphitic Carbon Nitride as a High-Performance Anode Material for Sodium Ion Batteries.Energy & Environmental Materials,2022, 5: 608–616.(邀稿,2022影響因子:15)

  19. Y. Zhang, J. Chen, C. Su, K. Chen, H. Zhang, Y. Yang,W. Huang*, Enhanced ionic diffusion interface in hierarchical metal-organic framework@layered double hydroxide for high-performance hybrid supercapacitors,Nano Research,2022, 15(10), 8983-8990.(2022影響因子:9.9)

  20. W. Huang*, J. Chen, W. Gao, L. Wang, P. Liu*, Y. Zhang, Z. Yin, Y. Yang, “Host-Guest” crystalline Mo/Co-framework induced phase-conversion of MoCx in carbon hybrids for regulating absorption of electromagnetic wave,Carbon,2022, 197: 129-140.(2022影響因子:10.9)

  21. W. Huang*, S. Wang, X. Yang, X. Zhang, Y. Zhang, K. Pei, R. Che*, Temperature induced transformation of Co@C nanoparticle in 3D hierarchical core-shell nanofiber network for enhanced electromagnetic wave adsorption,Carbon,2022, 195: 44-56.(2022影響因子:10.9)

  22. W. Huang*, Z. Chen, H. Wang, L. Wang, H. Zhang, and H. Wang, Sponge-like hierarchical porous carbon decorated by Fe atoms for high-efficient sodium storage and diffusion.Chemical Communications,2022, 58(28), 4496-4499.(2022影響因子:4.9)

  23. Y. Zhang, C. Su, J. Chen,W. Huang*and R. Lou, Recent progress of transition metal-based biomass-derived carbon composites for supercapacitor,Rare metals,2022,10.1007/s12598-022-02142-7.(2022影響因子:8.8)

  24. Z. He, Z. Zhou, P. Wei, T. Xu, J. Han, K. Huang, K. Guo*,W. Huang*, T. Akasaka, X. Lu*, Fullerene-Derived Porous and Defective N-Doped Carbon Nanosheets as Advanced Trifunctional Metal-Free Electrocatalysts,Chemistry - An Asian Journal,2022, 202200994.(2022影響因子:4.1)

  25. 2021年

  26. W. Huang*, X. Li, X. Yang*, H. Zhang, P. Liu, Y. Ma, and X. Lu, CeO2-embedded mesoporous CoS/MoS2as highly efficient and robust oxygen evolution electrocatalyst.Chemical Engineering Journal,2021, 420: 127595.(2022影響因子:15.1)

  27. W. Huang*, X. Li, X. Yang*, X. Zhang, H. Wang, The recent progress and perspectives on the metal- and covalent- organic frameworks based solid-state electrolytes for lithium-ion batteries.Materials Chemistry Frontiers,2021, 5 (9): 3593-3613.(邀稿,2022影響因子:7.0)

  28. W. Huang*, X. Li, X. Yang, H. Zhang, F. Wang, J. Zhang*. High-Efficient Electrocatalyst for Overall Water Splitting: Mesoporous CoS/MoS2with Hetero-Interface.Chemical Communications,2021, 57: 4847-4850.(2022影響因子:4.9)

  29. W. Huang*, Q. Li, D. Yu, Y. Tang, D. Lin, F. Wang*, J. Zhang*, Hybrid Zeolitic Imidazolate Frameworks for Promoting Electrocatalytic Oxygen Evolution via a Dual-Site Relay Mechanism.Inorganic Chemistry,2021, 60(5): 3074-3081.(2022影響因子:4.6)

  30. X. Yang, Y. Yan, W. Wang, Z. Hao, W. Zhang*,W. Huang*, Y. Wang, A 2-Fold Interpenetrated Nitrogen-Rich Metal–Organic Framework: Dye Adsorption and CO2Capture and Conversion.Inorganic Chemistry.2021,60(5): 3156-3164(2022影響因子:4.6)

  31. W. Huang*, X. X. Zhang and Y. N. Zhao, Recent progress and perspectives on the structural design on metal-organic zeolite (MOZ) frameworks.Dalton Transactions,2021, 50: 15-28.(邀稿,2022影響因子:4.0)

  32. Y. Zhang, J. Chen, C. Su,W. Huang*, A multifunctional cadmium-based metal-organic framework from a tricarboxylate ligand showing sensing and sensitization.Journal of Solid State Chemistry,2021, 302: 122407.(2022影響因子:3.3)

  33. C. Zuo, F. Zhao, Z. Tang, L. Zhang, Q. Niu, G. Cao, L. Zhao,W. Huang*, and P. Zhao*, Bi2O3gated Fe3O4@ZrO2core/shell drug delivery system for chemo/ionic synergistic therapeutics.Journal of Solid State Chemistry,2021, 303: 122489.(2022影響因子:3.3)

  34. 2020年

  35. P. Liu*, S. Gao, Y. Wang, Y. Huang, W. He,W. Huang, J. Luo, Carbon nanocages with N-doped carbon inner shell and Co/N-doped carbon outer shell as electromagnetic wave absorption materials,Chemical Engineering Journal,2020, 381: 122653.(高被引論文)(2022影響因子:15.1)

  36. T. Xu, W. Shen,W. Huang*, and X. Lu*. Fullerene Micro/Nanostructures: Controlled Synthesis and Energy Applications.Materials Today Nano,2020, 11:100081.(邀稿,2022影響因子:10.3)

  37. W. Huang*, X. Zhang, Y. Zhao, J. Zhang, and P. Liu*, Hollow N-doped carbon polyhedrons embedded Co and Mo2C nanoparticles for high-efficiency and wideband microwave absorption.Carbon,2020, 167: 19-30.(高被引論文,熱點(diǎn)論文)(2022影響因子:10.9)

  38. P. Liu*, S. Gao, Y. Wang, F. Zhou, Y. Huang,W. Huang*, and N. Chang, Core-shell Ni@C encapsulated by N-doped carbon derived from nickel-organic polymer coordination composites with enhanced microwave absorption.Carbon,2020, 170: 503-516.(高被引論文,熱點(diǎn)論文)(2022影響因子:10.9)

  39. P. Liu*, S. Gao,W. Huang*, J. Ren, D. Yu, and W. He, Hybrid zeolite imidazolate framework derived N-implanted carbon polyhedrons with tunable heterogeneous interfaces for strong wideband microwave attenuation.Carbon,2020, 159: 83-93.(高被引論文)(2022影響因子:10.9)

  40. W. Huang*, X. Li, D. Yu, X. Yang, L. Wang, P. Liu, and J. Zhang, CoMo-bimetallic N-doped porous carbon materials embedded with highly dispersed Pt nanoparticles as pH-universal hydrogen evolution reaction electrocatalyst.Nanoscale,2020, 12: 19804-19813.(2022影響因子:6.7)

  41. T. Xu, D. Yu, Z. Du,W. Huang*, and X. Lu, Two-Dimensional Mesoporous Carbon Materials Derived from Fullerene Microsheets for Energy Applications.Chemistry-A European Journal,2020, 26: 10811.(2022影響因子:4.3)

  42. K. Zhong, R. Yang, W. Zhang*, Y. Yan, X. Gou,W. Huang*,and Y.-Y. Wang, Zeolitic Metal Cluster Carboxylic Framework for Selective Carbon Dioxide Chemical Fixation through the Superlarge Cage.Inorganic Chemistry,2020, 59: 3912-3918.(2022影響因子:4.6)

  43. Y. Zhang*,Y. Zhang, L. Li, J. Chen, P. Li,W. Huang*. One-step in situ growth of high-density POMOFs films on carbon cloth for the electrochemical detection of bromate.Journal of Electroanalytical Chemistry,2020, 861: 113939.(2022影響因子:4.5)

    (核稿:黃文歡 編輯:趙誠(chéng))

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